1 00:00:06,470 --> 00:00:03,110 hello i'm suns kenosaki 2 00:00:08,629 --> 00:00:06,480 a master student at lc tokyo tech 3 00:00:09,990 --> 00:00:08,639 it is a great honor to be able to speak 4 00:00:11,990 --> 00:00:10,000 to you today 5 00:00:13,509 --> 00:00:12,000 i'd like to thank the organizers for 6 00:00:17,109 --> 00:00:13,519 choosing my abstract 7 00:00:19,429 --> 00:00:17,119 for live streaming today i'll give you a 8 00:00:21,029 --> 00:00:19,439 presentation of the results of high 9 00:00:24,150 --> 00:00:21,039 pressure viscosity measurements 10 00:00:25,429 --> 00:00:24,160 of mgsl4 solutions which is one of the 11 00:00:27,589 --> 00:00:25,439 possible compositions 12 00:00:28,630 --> 00:00:27,599 of the subsurface ocean of isis 13 00:00:30,790 --> 00:00:28,640 satellites 14 00:00:31,750 --> 00:00:30,800 and some implications for these 15 00:00:34,790 --> 00:00:31,760 environments 16 00:00:38,470 --> 00:00:34,800 and habitability first 17 00:00:40,630 --> 00:00:38,480 i would like to introduce icy satellites 18 00:00:43,510 --> 00:00:40,640 ic satellites are the major type of 19 00:00:47,110 --> 00:00:43,520 satellites of outer solar system planets 20 00:00:49,750 --> 00:00:47,120 and composed mainly of ice and rocks 21 00:00:51,110 --> 00:00:49,760 with the research progress it has become 22 00:00:54,389 --> 00:00:51,120 highly probable that 23 00:00:58,150 --> 00:00:54,399 some big isis attracts such as ganymede 24 00:01:01,029 --> 00:00:58,160 europa and titan have an ocean 25 00:01:03,750 --> 00:01:01,039 of liquid water underneath the thick ice 26 00:01:06,149 --> 00:01:03,760 crust covering the surface 27 00:01:07,350 --> 00:01:06,159 understanding this ocean environment is 28 00:01:09,910 --> 00:01:07,360 an important topic 29 00:01:11,429 --> 00:01:09,920 because it can lead to discussions on 30 00:01:14,710 --> 00:01:11,439 the diversity 31 00:01:19,670 --> 00:01:14,720 material cycle evolution 32 00:01:24,630 --> 00:01:22,630 what is the ocean environment like this 33 00:01:27,190 --> 00:01:24,640 figure is the pressure and temperature 34 00:01:30,630 --> 00:01:27,200 phase diagram of pure water 35 00:01:32,469 --> 00:01:30,640 markers on the vertical axis indicates 36 00:01:35,270 --> 00:01:32,479 the pressure of the boundary 37 00:01:36,310 --> 00:01:35,280 between the hydrosphere hydrosphere and 38 00:01:40,069 --> 00:01:36,320 the rocky layer 39 00:01:44,149 --> 00:01:40,079 of each body earth europa 40 00:01:46,789 --> 00:01:44,159 titan and climate as you can see here 41 00:01:47,749 --> 00:01:46,799 the ocean on these icy satellites has a 42 00:01:51,350 --> 00:01:47,759 larger 43 00:01:53,590 --> 00:01:51,360 maximum pressure than the earth's ocean 44 00:01:55,030 --> 00:01:53,600 and reaches one giga pascal in some 45 00:01:57,109 --> 00:01:55,040 satellite 46 00:01:59,510 --> 00:01:57,119 the assumed pressure temperature 47 00:02:00,950 --> 00:01:59,520 condition inside the icy satellites are 48 00:02:04,469 --> 00:02:00,960 shaded in blue 49 00:02:06,469 --> 00:02:04,479 and conditions of the ocean are shaded 50 00:02:09,270 --> 00:02:06,479 in that 51 00:02:11,670 --> 00:02:09,280 it should be noted that the actual ocean 52 00:02:14,790 --> 00:02:11,680 contains a variety of salt 53 00:02:18,150 --> 00:02:14,800 which lower the melting point somewhat 54 00:02:20,790 --> 00:02:18,160 and broadened the condition of the ocean 55 00:02:21,589 --> 00:02:20,800 the composition of the ocean has been 56 00:02:24,630 --> 00:02:21,599 discussed 57 00:02:27,270 --> 00:02:24,640 from various viewpoints such as surface 58 00:02:31,030 --> 00:02:27,280 composition 59 00:02:32,710 --> 00:02:31,040 in this study we focus on mgso4 60 00:02:35,589 --> 00:02:32,720 magnesium sulfate 61 00:02:36,150 --> 00:02:35,599 as one of the possible compositions for 62 00:02:38,790 --> 00:02:36,160 more 63 00:02:40,869 --> 00:02:38,800 accurate view of the ocean environment 64 00:02:44,070 --> 00:02:40,879 it is essential to understand 65 00:02:44,790 --> 00:02:44,080 how the ocean fluid behaves and the low 66 00:02:48,790 --> 00:02:44,800 temperature 67 00:02:54,630 --> 00:02:51,589 here i will focus on viscosity as one of 68 00:02:56,550 --> 00:02:54,640 the essential properties of the fluid 69 00:02:58,149 --> 00:02:56,560 this property determines material 70 00:03:01,190 --> 00:02:58,159 transport by diffusion 71 00:03:04,149 --> 00:03:01,200 and how fluid moves viscosity 72 00:03:06,390 --> 00:03:04,159 is dependent on pressure temperature and 73 00:03:09,670 --> 00:03:06,400 composition 74 00:03:13,190 --> 00:03:09,680 the figure shows the change in viscosity 75 00:03:15,350 --> 00:03:13,200 by adding various salt to water 76 00:03:17,110 --> 00:03:15,360 where the horizontal axis is the 77 00:03:20,229 --> 00:03:17,120 concentration 78 00:03:21,030 --> 00:03:20,239 and the vertical axis is the relative 79 00:03:24,470 --> 00:03:21,040 viscosity 80 00:03:27,990 --> 00:03:24,480 to water in particular 81 00:03:31,509 --> 00:03:28,000 the effect of mgs cell 4 on viscosity 82 00:03:34,149 --> 00:03:31,519 is very large in other words 83 00:03:35,750 --> 00:03:34,159 if the subsurface ocean contains a lot 84 00:03:39,190 --> 00:03:35,760 of mgso4 85 00:03:41,910 --> 00:03:39,200 the viscosity of the ocean fluid may be 86 00:03:43,350 --> 00:03:41,920 completely different from the pure water 87 00:03:47,110 --> 00:03:43,360 ocean 88 00:03:48,869 --> 00:03:47,120 however the there are no viscosity data 89 00:03:52,470 --> 00:03:48,879 under the temperature and pressure 90 00:03:56,550 --> 00:03:54,869 therefore this study aims to determine 91 00:03:58,390 --> 00:03:56,560 the temperature under pressure 92 00:04:01,429 --> 00:03:58,400 dependence of viscosity 93 00:04:03,589 --> 00:04:01,439 of aggregate mgso4 solutions at low 94 00:04:07,670 --> 00:04:03,599 temperature and high temp high pressure 95 00:04:10,149 --> 00:04:07,680 which can be applied to icy satellites 96 00:04:12,390 --> 00:04:10,159 in this study the viscosity of a 10 97 00:04:13,429 --> 00:04:12,400 weight percent acquires mgso for 98 00:04:16,469 --> 00:04:13,439 solution 99 00:04:18,390 --> 00:04:16,479 in these conditions 100 00:04:21,189 --> 00:04:18,400 was measured by the following sphere 101 00:04:25,430 --> 00:04:21,199 method using a diamond ambient cell 102 00:04:27,030 --> 00:04:25,440 a high pressure generator as shown here 103 00:04:29,030 --> 00:04:27,040 the temperature was controlled 104 00:04:32,230 --> 00:04:29,040 controlled by throwing hot 105 00:04:34,390 --> 00:04:32,240 and cold water through the dark and 106 00:04:38,230 --> 00:04:34,400 the pressure was determined using the 107 00:04:42,469 --> 00:04:40,310 the principle of the following sphere 108 00:04:45,430 --> 00:04:42,479 method is simple 109 00:04:46,790 --> 00:04:45,440 this method obtains a fluid viscosity by 110 00:04:49,749 --> 00:04:46,800 measuring the 111 00:04:51,110 --> 00:04:49,759 velocity of a falling sphere through the 112 00:04:54,390 --> 00:04:51,120 fluid 113 00:04:56,070 --> 00:04:54,400 this working equation is derived by 114 00:04:59,430 --> 00:04:56,080 considering the balance 115 00:05:00,390 --> 00:04:59,440 of gravity variancy and viscous 116 00:05:02,790 --> 00:05:00,400 resistance 117 00:05:05,430 --> 00:05:02,800 on the falling sphere and device 118 00:05:12,150 --> 00:05:05,440 collection factor 119 00:05:14,469 --> 00:05:12,160 a is the radius of the sphere 120 00:05:15,510 --> 00:05:14,479 rho is the density of the sphere and 121 00:05:18,870 --> 00:05:15,520 fluid 122 00:05:21,909 --> 00:05:18,880 respectively and g 123 00:05:27,670 --> 00:05:21,919 is the gravitational acceleration 124 00:05:31,110 --> 00:05:29,830 to acquire the velocity of the falling 125 00:05:35,029 --> 00:05:31,120 sphere in the dark 126 00:05:38,070 --> 00:05:35,039 i constructed this system this is a 127 00:05:39,110 --> 00:05:38,080 simplified image of the system and this 128 00:05:41,350 --> 00:05:39,120 is a 129 00:05:43,189 --> 00:05:41,360 picture of the dark diamond angle cell 130 00:05:46,870 --> 00:05:43,199 used in the experiment 131 00:05:49,590 --> 00:05:46,880 and a photo inside the cell 132 00:05:50,790 --> 00:05:49,600 the diamond army cell is mounted on a 133 00:05:53,590 --> 00:05:50,800 rotating stage 134 00:05:55,510 --> 00:05:53,600 and each rotation of the stage brings 135 00:05:58,870 --> 00:05:55,520 the sphere from the bottom 136 00:06:02,150 --> 00:05:58,880 to the top of the sample chamber 137 00:06:06,870 --> 00:06:02,160 then it can be dropped using 138 00:06:10,309 --> 00:06:06,880 light microscope and camera 139 00:06:12,790 --> 00:06:10,319 i monitored and recorded the drop motion 140 00:06:16,870 --> 00:06:12,800 then i measured the velocity of the 141 00:06:19,990 --> 00:06:16,880 sphere and calculated the viscosity 142 00:06:23,029 --> 00:06:20,000 let's move on to the result the plot 143 00:06:23,749 --> 00:06:23,039 on the left figure show the experimental 144 00:06:26,469 --> 00:06:23,759 results 145 00:06:26,790 --> 00:06:26,479 viscosity of magnesium sulfate solution 146 00:06:33,749 --> 00:06:26,800 at 147 00:06:37,749 --> 00:06:33,759 reference 148 00:06:42,390 --> 00:06:37,759 the viscosity value acquired ranged from 149 00:06:44,550 --> 00:06:42,400 1 to 10 meter pascal seconds 150 00:06:47,510 --> 00:06:44,560 on the right figure the viscosity of 151 00:06:50,790 --> 00:06:47,520 pure water is shown as a dashed line 152 00:06:53,909 --> 00:06:50,800 for comparison and the viscosity of 153 00:06:57,270 --> 00:06:53,919 various aqueous electro 154 00:07:01,350 --> 00:06:57,280 light solutions by reference is shown 155 00:07:01,589 --> 00:07:01,360 as a dotted line as with the viscosity 156 00:07:04,950 --> 00:07:01,599 of 157 00:07:06,150 --> 00:07:04,960 other accuracy mgso aqueous electrolyte 158 00:07:08,390 --> 00:07:06,160 solutions 159 00:07:10,870 --> 00:07:08,400 the pressure dependence of the viscosity 160 00:07:13,749 --> 00:07:10,880 of magnesium sulfate solution 161 00:07:14,230 --> 00:07:13,759 can be fitted by the quadratic equation 162 00:07:17,990 --> 00:07:14,240 shown 163 00:07:20,230 --> 00:07:18,000 by the solid line at all temperatures 164 00:07:21,270 --> 00:07:20,240 the viscosity of magnesium sulfate 165 00:07:26,710 --> 00:07:21,280 solution is 166 00:07:30,629 --> 00:07:28,710 using the pressure and temperature 167 00:07:33,270 --> 00:07:30,639 dependence of viscosity 168 00:07:34,230 --> 00:07:33,280 of the end in this study i calculated 169 00:07:37,270 --> 00:07:34,240 the viscosity 170 00:07:37,990 --> 00:07:37,280 at a given temperature and pressure i 171 00:07:41,670 --> 00:07:38,000 draw 172 00:07:44,469 --> 00:07:41,680 iso viscosity lines on the phase diagram 173 00:07:46,230 --> 00:07:44,479 of 10 weight percent magnesium sulphate 174 00:07:48,790 --> 00:07:46,240 solution 175 00:07:50,790 --> 00:07:48,800 the shaded area represents the 176 00:07:54,150 --> 00:07:50,800 temperature and pressure range of the 177 00:08:01,189 --> 00:07:57,430 while the viscosity of pure water ocean 178 00:08:05,589 --> 00:08:01,199 shown in the right figure is around 179 00:08:08,790 --> 00:08:05,599 1 or 2 meter pascal seconds the ocean of 180 00:08:11,749 --> 00:08:08,800 10 weight percent mgso4 solutions 181 00:08:13,430 --> 00:08:11,759 can vary from 1 to 10 mega pascal 182 00:08:16,230 --> 00:08:13,440 seconds 183 00:08:19,830 --> 00:08:16,240 one digit valuation depending on the 184 00:08:23,830 --> 00:08:22,390 i showed that viscosity of subsurface 185 00:08:27,029 --> 00:08:23,840 ocean fluid may be 186 00:08:29,110 --> 00:08:27,039 highly variable one digit in the case of 187 00:08:31,589 --> 00:08:29,120 10 weight percent of energy software 188 00:08:34,709 --> 00:08:31,599 solutions 189 00:08:36,469 --> 00:08:34,719 so i will introduce some implications 190 00:08:38,870 --> 00:08:36,479 for iso satellites 191 00:08:39,670 --> 00:08:38,880 this is the simplified cross-sectional 192 00:08:41,990 --> 00:08:39,680 installation 193 00:08:42,709 --> 00:08:42,000 of isosatellites with some possible 194 00:08:47,190 --> 00:08:42,719 phenomena 195 00:08:50,150 --> 00:08:47,200 related to viscosity and habitability 196 00:08:51,509 --> 00:08:50,160 viscosity relates to how ocean fluid 197 00:08:54,389 --> 00:08:51,519 moves 198 00:08:55,670 --> 00:08:54,399 it affects the convection style of the 199 00:08:59,350 --> 00:08:55,680 subsurface ocean 200 00:09:03,190 --> 00:08:59,360 and fluid movement velocity 201 00:09:04,949 --> 00:09:03,200 through rocks and ices 202 00:09:07,190 --> 00:09:04,959 therefore the time scale of 203 00:09:09,829 --> 00:09:07,200 differentiation of these bodies and 204 00:09:12,870 --> 00:09:09,839 photo saturation 205 00:09:14,949 --> 00:09:12,880 from an astrobiological point of view 206 00:09:18,310 --> 00:09:14,959 diffusion is one of the important 207 00:09:20,070 --> 00:09:18,320 keywords related to viscosity 208 00:09:21,509 --> 00:09:20,080 the diffusion coefficient in the 209 00:09:24,550 --> 00:09:21,519 solution can be 210 00:09:27,590 --> 00:09:24,560 written as the stocks einstein equation 211 00:09:31,430 --> 00:09:27,600 which says the diffusion coefficient is 212 00:09:34,070 --> 00:09:31,440 inversely proportional to the viscosity 213 00:09:34,470 --> 00:09:34,080 therefore viscosity variation affects 214 00:09:37,030 --> 00:09:34,480 the 215 00:09:37,910 --> 00:09:37,040 efficiency of material transport by 216 00:09:42,230 --> 00:09:37,920 diffusion 217 00:09:46,070 --> 00:09:42,240 the right process 218 00:09:49,590 --> 00:09:46,080 such as nutrient transportation 219 00:09:52,150 --> 00:09:49,600 let's move on to the protein as you know 220 00:09:52,870 --> 00:09:52,160 proteins are large molecules and are 221 00:09:56,389 --> 00:09:52,880 composed 222 00:09:59,430 --> 00:09:56,399 of long chains of amino acid 223 00:10:03,269 --> 00:09:59,440 in a solution proteins have 224 00:10:06,550 --> 00:10:03,279 variable structures in proteins 225 00:10:09,910 --> 00:10:06,560 processes such as folding and catalysis 226 00:10:10,870 --> 00:10:09,920 slowed by solution viscosity around the 227 00:10:17,590 --> 00:10:10,880 protein 228 00:10:22,150 --> 00:10:20,150 now let me touch on the implication 229 00:10:24,550 --> 00:10:22,160 based on the study of the prebiotic 230 00:10:27,990 --> 00:10:24,560 chemistry on the earth 231 00:10:29,829 --> 00:10:28,000 when a double strand like dna diffuses 232 00:10:32,470 --> 00:10:29,839 apart 233 00:10:33,750 --> 00:10:32,480 high viscosity makes it difficult for 234 00:10:36,670 --> 00:10:33,760 these strands to 235 00:10:37,829 --> 00:10:36,680 rebind again allowing small 236 00:10:42,949 --> 00:10:37,839 oligonucleotides 237 00:10:46,069 --> 00:10:42,959 to bind each strand for replication 238 00:10:49,030 --> 00:10:46,079 although this study assumes much higher 239 00:10:49,910 --> 00:10:49,040 solvent viscosity than measured in my 240 00:10:52,550 --> 00:10:49,920 study 241 00:10:53,430 --> 00:10:52,560 and its discussion includes temperature 242 00:10:56,630 --> 00:10:53,440 increase and 243 00:10:57,829 --> 00:10:56,640 decreasing degree cycle this has an 244 00:11:00,630 --> 00:10:57,839 implication for the 245 00:11:02,150 --> 00:11:00,640 possible biologic process under the high 246 00:11:06,310 --> 00:11:02,160 viscosity condition 247 00:11:13,829 --> 00:11:10,069 in summary viscosity variation 248 00:11:16,310 --> 00:11:13,839 of the subsurface ocean fluid one digit 249 00:11:17,350 --> 00:11:16,320 in the case of thin weight-based mgso4 250 00:11:20,230 --> 00:11:17,360 solutions 251 00:11:22,470 --> 00:11:20,240 occur due to pressure temperature and 252 00:11:24,870 --> 00:11:22,480 concentration change 253 00:11:26,150 --> 00:11:24,880 which might affect convection 254 00:11:32,310 --> 00:11:26,160 differentiation